4-Chloroanilinium perchlorate–18-crown-16 (1/1)

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4-Chloro­anilinium perchlorate–18-crown-16 (1/1)

In the title compound, C(6)H(7)ClN(+)·ClO(4) (-)·C(12)H(24)O(6), the cation forms a 1:1 complex with the crown ether, viz [C(6)H(7)ClN-(18-crown-6)](+), in which the -NH(3) (+) unit nests in the crown and inter-acts with it through bifurcated N-H⋯O hydrogen bonding. All constituents of the structure have crystallographically imposed mirror symmetry except for the H atoms of the -NH(3) (+) group...

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Synthesis, structure and metal ion binding of di-(1,8-naphtho)-16-crown-4 compounds

The syntheses of two di(1,8-naphtho)-16-crown-4 compounds are described. In the X-ray structure of di(1,8-naphtho)-16-crown-4, the compound crystallizes in the orthorhombic space group Pna21 with four molecules per asymmetric unit. Alkali metal cation selectivities of the ionophores are assessed in solvent polymeric membrane electrodes.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2011

ISSN: 1600-5368

DOI: 10.1107/s1600536811048859